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Title: Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes
Author: Saladrigas, Mar
Puig Bosch, Jordi
Bonjoch i Sesé, Josep
Bradshaw, Ben
Keywords: Alquens
Enllaços químics
Química orgànica
Chemical bonds
Organic chemistry
Issue Date: 5-Oct-2020
Publisher: American Chemical Society
Abstract: The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes, employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes as viable acceptor groups in MHAT reactions. The insights gained in this study led to the reexamination of the previously reported intramolecular version of the reaction, and the addition of FeII salts allowed the development of a more efficient second-generation approach.
Note: Versió postprint del document publicat a:
It is part of: Organic Letters, 2020, vol. 22, p. 8111-8115
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ISSN: 1523-7060
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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