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http://hdl.handle.net/2445/184042
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DC Field | Value | Language |
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dc.contributor.author | Casanovas, Berta | - |
dc.contributor.author | Porcar Santos, Oriol | - |
dc.contributor.author | Speed Castro, Saskia | - |
dc.contributor.author | Vicente Castillo, Ramón | - |
dc.contributor.author | Font Bardia, Ma. Mercedes | - |
dc.contributor.author | Salah El Fallah, Mohamed | - |
dc.date.accessioned | 2022-03-11T15:40:17Z | - |
dc.date.available | 2022-03-11T15:40:17Z | - |
dc.date.issued | 2021 | - |
dc.identifier.issn | 2312-7481 | - |
dc.identifier.uri | http://hdl.handle.net/2445/184042 | - |
dc.description.abstract | Five new mononuclear lanthanide complexes are synthesized by adding the several lanthanide nitrate hexahydrate salts, which for lanthanide (Ln) are Eu, Tb, Dy, Er, and Yb, with 9-anthracenecarboxylic acid (9-Hanthc) and 2,20 :6,200-terpyridine (TPY) in mixed solution of methanol and dimethylformamide (DMF). The general formula is [Eu(9-anthc)3 (TPY)(DMF)]·H2O (1Eu) where Eu(III) is ennea-coordinated or [Ln(9-anthc)3 (TPY)(H2O)]·H2O·DMF (Ln = Tb (2Tb), Dy (3Dy), Er (4Er), and Yb (5Yb)) where Ln(III) is octa-coordinated. For compounds 3Dy, 4Er, and 5Yb, the dynamic ac magnetic study indicated field-induced single molecule magnet (SMM) behavior. The photoluminescence studies in the solid state of these complexes show the sensitization of 4f-4f transitions for 4Er and 5Yb in the NIR region. | - |
dc.format.extent | 14 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | MDPI | - |
dc.relation.isformatof | Reproducció del document publicat a: https://doi.org/10.3390/magnetochemistry7090124 | - |
dc.relation.ispartof | Magnetochemistry, 2021, vol. 7, num. 9, p. 124-137 | - |
dc.relation.uri | https://doi.org/10.3390/magnetochemistry7090124 | - |
dc.rights | cc-by (c) Casanovas, Berta et al., 2021 | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Magnetisme | - |
dc.subject.classification | Luminescència | - |
dc.subject.classification | Compostos de coordinació | - |
dc.subject.other | Magnetism | - |
dc.subject.other | Luminescence | - |
dc.subject.other | Coordination compounds | - |
dc.title | Field-Induced SMM and Vis/NIR Luminescence on mononuclear lanthanide complexes with 9-Anthracenecarboxylate and 2,2':6,2'-Terpyridine. | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/publishedVersion | - |
dc.identifier.idgrec | 717909 | - |
dc.date.updated | 2022-03-11T15:40:17Z | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) |
Files in This Item:
File | Description | Size | Format | |
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717909.pdf | 2.02 MB | Adobe PDF | View/Open |
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