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http://hdl.handle.net/2445/185089
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DC Field | Value | Language |
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dc.contributor.author | Aragonès, Albert C. | - |
dc.contributor.author | Martín Rodríguez, Alejandro | - |
dc.contributor.author | Aravena Ponce, Daniel Alejandro | - |
dc.contributor.author | Di Palma, Giuseppe | - |
dc.contributor.author | Qian, Wenjie | - |
dc.contributor.author | Puigmartí-Luis, Josep | - |
dc.contributor.author | Aliaga-Alcalde, Núria | - |
dc.contributor.author | González Campo, Arántzazu | - |
dc.contributor.author | Díez Pérez, Ismael | - |
dc.contributor.author | Ruiz Sabín, Eliseo | - |
dc.date.accessioned | 2022-04-22T14:39:15Z | - |
dc.date.available | 2022-12-01T06:10:31Z | - |
dc.date.issued | 2021-12-01 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | http://hdl.handle.net/2445/185089 | - |
dc.description.abstract | Here we present room-temperature spin-dependent charge transport measurements in single-molecule junctions made of metalloporphyrin-based supramolecular assemblies. They display large conductance switching for magnetoresistance in a single-molecule junction. The magnetoresistance depends acutely on the probed electron pathway through the supramolecular wire: those involving the metal center showed marked magnetoresistance effects as opposed to those exclusively involving the porphyrin ring which present nearly complete absence of spin-dependent charge transport. The molecular junction magnetoresistance is highly anisotropic, being observable when the magnetization of the ferromagnetic junction electrode is oriented along the main molecular junction axis, and almost suppressed when it is perpendicular. The key ingredients for the above effect to manifest are the electronic structure of the paramagnetic metalloporphyrin, and the spinterface created at the molecule-electrode contact. | - |
dc.format.extent | 8 p. | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | - |
dc.publisher | Wiley-VCH | - |
dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1002/anie.202110515 | - |
dc.relation.ispartof | Angewandte Chemie-International Edition, 2021, vol. 60, num. 49, p. 25958-25965 | - |
dc.relation.uri | https://doi.org/10.1002/anie.202110515 | - |
dc.rights | (c) Wiley-VCH, 2021 | - |
dc.source | Articles publicats en revistes (Química Inorgànica i Orgànica) | - |
dc.subject.classification | Teoria del funcional de densitat | - |
dc.subject.classification | Magnetoresistència | - |
dc.subject.classification | Porfirines | - |
dc.subject.other | Density functionals | - |
dc.subject.other | Magnetoresistance | - |
dc.subject.other | Porphyrins | - |
dc.title | Room-Temperature Spin-Dependent Transport in Metalloporphyrin-Based Supramolecular Wires | - |
dc.type | info:eu-repo/semantics/article | - |
dc.type | info:eu-repo/semantics/acceptedVersion | - |
dc.identifier.idgrec | 720156 | - |
dc.date.updated | 2022-04-22T14:39:15Z | - |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/724981/EU//Tmol4TRANS | - |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/772391/EU//Fields4CAT | - |
dc.relation.projectID | info:eu-repo/grantAgreement/EC/H2020/844668/EU//TECh-MoDE | - |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | - |
Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Publicacions de projectes de recerca finançats per la UE |
Files in This Item:
File | Description | Size | Format | |
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720156.pdf | 687.89 kB | Adobe PDF | View/Open |
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