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https://hdl.handle.net/2445/216765| Title: | Synthesis, crystal structures and properties of cis- and trans-isomers of [Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] (R1 = H or Cl) |
| Author: | López Martínez, Ma. Concepción Moya Álvarez, Carlos Basu, Pradipta K. González Gazulla, Asensio Solans-Monfort, Xavier Font Bardia, Ma. Mercedes Calvet Pallàs, Maria Teresa Lalinde, Elena Moreno, M. Teresa |
| Keywords: | Cristal·lografia Luminescència Platí Crystallography Luminescence Platinum |
| Issue Date: | 27-Jul-2011 |
| Publisher: | Elsevier B.V. |
| Abstract: | The study of the reactivity of the 3-methoxyimino-2-phenyl-3H-indoles C6H4-4R1-1-[C8H4N-30-NOMe] [R1 = Cl (1a) or H (1b)] with cis-[PtCl2(dmso)2] has allowed the isolation of trans-[Pt{C6H4-4R1-1- [C8H4N-30-NOMe]}Cl2(dmso)] [R1 = Cl (2a) or H (2b)] and cis-[Pt{C6H4-4R1-1-[C8H4N-30-NOMe]}Cl2(dmso)] CH2Cl2 [R1 = Cl (3a) or H(3b)]. Their crystal structures confirm: (a) the existence of a PtANindole bond, (b) the relative arrangement of the Cl ligands (trans in 2a and 2b or cis in 3a and 3b) and (c) the anti- (E) configuration of the oxime. A comparative study of the spectroscopic and photo-optical properties of ligands and their platinum(II) complexes (2a, 2b, 3a and 3b) is also reported. |
| Note: | Versió postprint del document publicat a: https://doi.org/10.1016/j.molstruc.2011.05.030 |
| It is part of: | Journal of Molecular Structure, 2011, vol. 999, num.1-3, p. 49-59 |
| URI: | https://hdl.handle.net/2445/216765 |
| Related resource: | https://doi.org/10.1016/j.molstruc.2011.05.030 |
| ISSN: | 0022-2860 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Mineralogia, Petrologia i Geologia Aplicada) |
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|---|---|---|---|---|
| 144326.pdf | 1.45 MB | Adobe PDF | View/Open |
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