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https://hdl.handle.net/2445/68334| Title: | Stereospecific SN2@P reactions: Novel access to bulky P-stereogenic ligands |
| Author: | Orgué Gassol, Sílvia Flores-Gaspar, Areli Biosca, Maria Pàmies, Oscar Diéguez, Montserrat Riera i Escalé, Antoni Verdaguer i Espaulella, Xavier |
| Keywords: | Hidròlisi Lligands Catàlisi asimètrica Compostos de bor Hydrolysis Ligands Enantioselective catalysis Boron compounds |
| Issue Date: | 2-Oct-2015 |
| Publisher: | Royal Society of Chemistry |
| Abstract: | The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands. |
| Note: | Reproducció del document publicat a: http://dx.doi.org/10.1039/c5cc07504a |
| It is part of: | Chemical Communications, 2015, vol. 51, p. 17548-17551 |
| URI: | https://hdl.handle.net/2445/68334 |
| Related resource: | http://dx.doi.org/10.1039/c5cc07504a |
| ISSN: | 1359-7345 |
| Appears in Collections: | Articles publicats en revistes (Química Inorgànica i Orgànica) Articles publicats en revistes (Institut de Recerca Biomèdica (IRB Barcelona)) |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| 654578.pdf | 1.41 MB | Adobe PDF | View/Open |
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