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Title: An Unexpected Oxidation in the Generation of Cyclopenta[c]piperidines by Ring-Closing Metathesis
Author: Amat Tusón, Mercedes
Brunaccini, Elisa
Checa Castaño, Begoña
Pérez Bosch, Maria
Llor Brunés, Núria
Bosch Cartes, Joan
Keywords: Lactames
Compostos bioactius
Química orgànica
Bioactive compounds
Organic chemistry
Issue Date: 2009
Publisher: American Chemical Society
Abstract: Ring-closing metathesis reaction of dienes A (n= 1, R= CO2R') leads to fused cyclopentenones C instead of the expected cyclopentene derivatives B. RCM reaction of the other dienes A takes place satisfactorily, affording the expected fused cycloalkene derivatives B. Cyclohexene B (n= 2, R= CO2R') also undergoes oxidation to the corresponding cyclohexenone C.
Note: Versió postprint del document publicat a:
It is part of: Organic Letters, 2009, vol. 11, p. 4370-4373
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ISSN: 1523-7060
Appears in Collections:Articles publicats en revistes (Nutrició, Ciències de l'Alimentació i Gastronomia)
Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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