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Title: 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
Author: Alcalde Pais, Ma. Ermitas (María de las Ermitas)
Mesquida Estévez, Ma. Neus
Alvarez-Rúa, Carmen
Cuberes, Rosa
Frigola Mas, Jordi
García-Granda, Santiago
Keywords: Radiocristal·lografia
X-ray crystallography
Issue Date: 2008
Publisher: MDPI
Abstract: The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and thecorresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 wereperformed in solution using 1H-NMR and in the solid state by X-ray crystallography,providing evidence of H-bonding networks. The crystal packing was controlled byhomomeric intermolecular oxime···oxime H-bond interactions for 6 and cooperativeoxime···N(pyridyl) and CH/π interactions for 7 and 9. Keywords: Oximes; ethanones; hydrogen bonds; self-assembly; X-ray diffraction crystalography
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It is part of: Molecules, 2008, vol. 13, p. 301-318
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ISSN: 1420-3049
Appears in Collections:Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

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