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Pattern formation during mesophase growth in a homologous series

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Remarkable differences in the shape of the nematic-smectic-B interface in a quasi-two-dimensional geometry have been experimentally observed in three liquid crystals of very similar molecular structure, i.e., neighboring members of a homologous series. In the thermal equilibrium of the two mesophases a faceted rectanglelike shape was observed with considerably different shape anisotropies for the three homologs. Various morphologies such as dendritic, dendriticlike, and faceted shapes of the rapidly growing smectic-B germ were also observed for the three substances. Experimental results were compared with computer simulations based on the phase field model. The pattern forming behavior of a binary mixture of two homologs was also studied.

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TÓTH-KATONA, T., BÖRZSÖNYI, T., VÁRADI, Z., SZABON, J., BUKA, Agnes, GONZÁLEZ CINCA, Ricard, RAMÍREZ PISCINA, Laureano, CASADEMUNT I VIADER, Jaume, HERNÁNDEZ MACHADO, Aurora. Pattern formation during mesophase growth in a homologous series. _Physical Review E_. 1996. Vol. 54, núm. 2, pàgs. 1574-1583. [consulta: 1 de febrer de 2026]. ISSN: 1539-3755. [Disponible a: https://hdl.handle.net/2445/18726]

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