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cc-by-nc (c) Santiago, Raul, 2024
Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/228405

Unlocking the predictive power of quantum-inspired representations for intermolecular properties in machine learning

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The quest for accurate and efficient Machine Learning (ML) models to predict complex molecular properties has driven the development of new quantum-inspired representations (QIR). This study introduces MODA (Molecular Orbital Decomposition and Aggregation), a novel QIR-class descriptor with enhanced predictive capabilities. By incorporating wave-function information, MODA is able to capture electronic structure intricacies, providing deeper chemical insight and improving performance in unsupervised and supervised learning tasks. Specially designed to be separable, the multi-moiety regularization technique unlocks the predictive power of MODA for both intra- and intermolecular properties, making it the first QIR-class descriptor capable of such distinction. We demonstrate that MODA shows the best performance for intermolecular magnetic exchange coupling (JAB) predictions among the descriptors tested herein. By offering a versatile solution to address both intra- and intermolecular properties, MODA showcases the potential of quantum-inspired descriptors to improve the predictive capabilities of ML- based methods in computational chemistry and materials discovery.

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SANTIAGO, Raul, et al. Unlocking the predictive power of quantum-inspired representations for intermolecular properties in machine learning. Digital Discovery. 2024. Vol. 3, núm. 1, pàgs. 99-112. ISSN 2635-098X. [consulta: 13 de maig de 2026]. Disponible a: https://hdl.handle.net/2445/228405

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