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Article

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Accepted version

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2020-10-05

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/173441

Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes

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https://doi.org/10.1021/acs.orglett.0c03081

Abstract

The intermolecular reductive radical coupling of aldehydes with nonactivated alkenes, employing metal hydride atom transfer (MHAT) catalysis with a combination of FeII and FeIII salts, is described. This constitutes the first use of aldehydes as viable acceptor groups in MHAT reactions. The insights gained in this study led to the reexamination of the previously reported intramolecular version of the reaction, and the addition of FeII salts allowed the development of a more efficient second-generation approach.

Subject

Alquens, Catàlisi, Enllaços químics, Química orgànica

Subject (English)

Alkenes, Catalysis, Chemical bonds, Organic chemistry

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

Citation

SALADRIGAS, Mar, et al. Iron-Catalyzed Radical Intermolecular Addition of Unbiased Alkenes to Aldehydes. Organic Letters. 2020. Vol. 22, num. 8111-8115. ISSN 1523-7060. [consulted: 15 of August of 2026]. Available at: https://hdl.handle.net/2445/173441

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