Relevant properties for catalytic activity of sulfonic ion-exchange resins in etherification of isobutene with linear primary alcohols

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dc.contributor.authorBadia i Córcoles, Jordi Hug
dc.contributor.authorFité Piquer, Carles
dc.contributor.authorBringué Tomàs, Roger
dc.contributor.authorRamírez Rangel, Eliana
dc.contributor.authorIborra Urios, Montserrat
dc.date.accessioned2022-06-17T15:51:08Z
dc.date.available2022-06-17T15:51:08Z
dc.date.issued2016-10-25
dc.date.updated2022-06-17T15:51:09Z
dc.description.abstractThe catalyzed liquid-phase reaction of isobutene with a homologous series of linear alcohols, from methanol to 1-butanol, has been studied at 333 K and 1.5 MPa. Sixteen sulfonic ion-exchange resins, to cover a wide range of properties, have been assayed. A response surface methodology analysis allowed to identify the most relevant catalyst properties, and the change of their relative importance along the homologous series of alcohols. Globally, reaction rates increase with the alcohol length. Resins with a high acid capacity and low specific volume of swollen polymer are the most active ones for the studied etherification reactions. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
dc.format.extent10 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec668699
dc.identifier.issn1226-086X
dc.identifier.urihttps://hdl.handle.net/2445/186770
dc.language.isoeng
dc.publisherElsevier
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.jiec.2016.07.025
dc.relation.ispartofJournal of Industrial and Engineering Chemistry, 2016, vol. 42, p. 36-45
dc.relation.urihttps://doi.org/10.1016/j.jiec.2016.07.025
dc.rightscc-by-nc-nd (c) Elsevier, 2016
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceArticles publicats en revistes (Enginyeria Química i Química Analítica)
dc.subject.classificationCatàlisi
dc.subject.classificationResines de bescanvi iònic
dc.subject.classificationAlcohols
dc.subject.otherCatalysis
dc.subject.otherIon exchange resins
dc.subject.otherAlcohols
dc.titleRelevant properties for catalytic activity of sulfonic ion-exchange resins in etherification of isobutene with linear primary alcohols
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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