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38277.pdf (1.77 MB)

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1994

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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/9751

Model for the emission of Si+ ions during oxygen bombardment of Si(100) surfaces

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Recurs relacionat

http://dx.doi.org/10.1103/PhysRevB.50.15015

Resum

The variation in the emission of Si+ ions from ion-beam-induced oxidized silicon surfaces has been studied. The stoichiometry and the electronic structure of the altered layer has been characterized using x-ray photoelectron spectroscopy (XPS). The XPS analysis of the Si 2p core level indicates the strong presence of suboxide chemical states when bombarding at angles of incidence larger than 30 °. Since the surface stoichiometry or degree of oxidation varies with the angle of incidence, the corresponding valence-band structures also differ among each other. A comparison between experimental measurements and theoretically calculated Si and SiO2 valence bands indicates that the valence bands for the altered layers are formed by a combination of those two. Since Si-Si bonds are present in the suboxide molecules, the top of the respective new valence bands are formed by the corresponding 3p-3p Si-like subbands, which extend up to the Si Fermi level. The changes in stoichiometry and electronic structure have been correlated with the emission of Si+ ions from these surfaces. From the results a general model for the Si+ ion emission is proposed combining the resonant tunneling and local-bond-breaking models.

Matèries

Impacte (Física), Fluorescència, Química de superfícies

Matèries (anglès)

Impact phenomena, Fluorescence and phosphorescence, Electron states at surfaces and interfaces

Citació

Col·leccions

Articles publicats en revistes (Enginyeria Electrònica i Biomèdica)

Citació

ALAY, Josep Lluís and VANDERVORST, Wilfried. Model for the emission of Si+ ions during oxygen bombardment of Si(100) surfaces. Physical Review B. 1994. Vol. 50, num. 20, pags. 15015-15025. ISSN 0163-1829. [consulted: 16 of August of 2026]. Available at: https://hdl.handle.net/2445/9751

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