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Magnetic transitions in Nd2NiO4

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Five different magnetic phase transitions have been identified and characterized in stoichiometric Nd 2 NiO 4 by means of magnetic-susceptibility and isothermal-magnetization measurements. A collinear antiferromagnetic ordering of Ni 2 + magnetic moments exists between T N 1 ≊320 K and T c 1 ≊130 K where an orthorhombic-to-tetragonal structural phase transition occurs. In this temperature range, Nd 3 + ions follow a simple paramagnetic Curie-Weiss-like behavior, while a weak ferromagnetic component appears below 130 K. An internal magnetic field on the Nd 3 + ions develops with this structural phase transition. Two additional transitions are observed at T c 2 ≊68 K and T c 3 ≊45 K which are characterized by a sudden increase of the weak ferromagnetic component. Finally, a peak of the differential susceptibility at T N 2 ≊11 K marks a long-range antiferromagnetic ordering of the Nd 3 + ions. The internal magnetic field acting on the Nd ions was evaluated to be 5.2 T in the 20 K– T c 2 temperature range.

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OBRADORS, Xavier, BATLLE GELABERT, Xavier, RODRÍGUEZ CARVAJAL, Juan, MARTÍNEZ, J. l., VALLET REGÍ, María, GONZÁLEZ CALBET, José maría, ALONSO, J. a. (julio a.). Magnetic transitions in Nd2NiO4. _Physical Review B_. 1991. Vol. 43, núm. 13, pàgs. 10451-10454. [consulta: 25 de febrer de 2026]. ISSN: 0163-1829. [Disponible a: https://hdl.handle.net/2445/9947]

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