Carregant...
Fitxers
Tipus de document
ArticleVersió
Versió publicadaData de publicació
Llicència de publicació
Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/164162
Theoretical characterization of transition state dynamical resonances in heavy-light-heavy reactions
Títol de la revista
Director/Tutor
ISSN de la revista
Títol del volum
Recurs relacionat
Resum
The resonant reactivity of three elementary Heavy-Light-Heavy reactions is presented and discussed. Collinear reactivity, in which a vibrational adiabatic model is constructed, is used for a detailed analysis of resonance phenomena, which appear as a direct consequence of transition state metastable states in the strong interaction region of the potential energy surface. Their influence on the detailed mechanism of the elementary process is also discussed. The shape of the resonant peak, and the phase and the Argand plot of the S-matrix are used for a further characterization.Three-dimensional approximate calculations are used to test the evolution of the energy dependent structure present in detailed quantities when sums and integrations over all partial waves contributing to reaction are taken into account to obtain the usual averaged global quantities such as integral state-to-state cross sections.
Matèries
Matèries (anglès)
Citació
Citació
AGUILAR NAVARRO, Antonio, ALBERTÍ I WIRSING, Margarida, BLASCO, R., GILIBERT, Miquel, GIMÉNEZ I FONT, Xavier, GONZÁLEZ PÉREZ, Miguel, LUCAS ALCORTA, José maría, PRIETO, M., SAYÓS ORTEGA, Ramón, SOLÉ, Albert (solé sabaté). Theoretical characterization of transition state dynamical resonances in heavy-light-heavy reactions. _Laser Chemistry_. 1991. Vol. 11, núm. 3-4, pàgs. 291-302. [consulta: 14 de gener de 2026]. ISSN: 0278-6273. [Disponible a: https://hdl.handle.net/2445/164162]