Carregant...
Fitxers
Tipus de document
ArticleVersió
Versió publicadaData de publicació
Tots els drets reservats
Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/192424
New insights about the structural properties of κ-(BEDT-TTF)2X2(CN)3 (X=Cu and Ag) Spin Liquids
Títol de la revista
Director/Tutor
ISSN de la revista
Títol del volum
Recurs relacionat
Resum
Here, the first accurate study is presented of the room-temperature and 100 K structures of one of the first organic spin liquids, -(BEDT-TTF)2Ag2(CN)3. It is shown that the monoclinic structure determined previously is only the average one. It is shown that the exact structure presents triclinic symmetry with two non-equivalent dimers in the unit cell. But surprisingly this does not lead to a sizeable charge disproportionation between dimers. The difference from the analogue compound -(BEDT-TTF)2Cu2(CN)3 which also presents a spin liquid phase is discussed in detail. The data provided here show the importance of the anionic layer and in particular the transition metal position in the process of symmetry breaking. The possible impact of the symmetry breaking, albeit weak, on the spin-liquid mechanism and the influence of various disorders on the physical properties of this system is also discussed.
Matèries
Matèries (anglès)
Citació
Citació
FOURY-LEYLEKIAN, Pascale, ILAKOVAC, Vita, FERTEY, Pierre, BALÉDENT, Victor, MILAT, Ognjen, MIYAGAWA, Kazuya, KANODA, Kazushi, HIRAMATSU, Takaaki, YOSHIDA, Yukihiro, SAITO, Gunzi, ALEMANY I CAHNER, Pere, CANADELL, Enric, TOMIC, Silvia, POUGET, Jean-paul. New insights about the structural properties of κ-(BEDT-TTF)2X2(CN)3 (X=Cu and Ag) Spin Liquids. _Acta Crystallographica Section B: Structural Science_. Crystal Engineering and Materials. Vol. 2020, núm. B76, pàgs. 4. [consulta: 24 de gener de 2026]. ISSN: 2052-5192. [Disponible a: https://hdl.handle.net/2445/192424]