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2014-01-06

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cc-by (c) Ghashghaei, Ouldouz et al., 2014
Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/120563

Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations

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https://doi.org/10.3762/bjoc.10.3

Abstract

The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon-nitrogen double bond of the imine to form the 4-membered ring system. The scope of the reaction regarding the imine and isocyanide ranges has been determined, and also some mechanistic variations and structural features have been described.

Subject

Isonitrils, Imines, Compostos heterocíclics, Reaccions químiques, Química orgànica

Subject (English)

Isocyanides, Imines, Heterocyclic compounds, Chemical reactions, Organic chemistry

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)

Citation

GHASHGHAEI, Ouldouz, et al. Studies on the Interaction of Isocyanides with Imines: Reaction Scope and Mechanistic Variations. Beilstein Journal of Organic Chemistry. 2014. Vol. 10, num. 12-17. ISSN 1860-5397. [consulted: 15 of August of 2026]. Available at: https://hdl.handle.net/2445/120563

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