Effects of Nb doping on the TiO2 anatase-to-rutile phase transition

dc.contributor.authorArbiol i Cobos, Jordicat
dc.contributor.authorCerdà Belmonte, Judithcat
dc.contributor.authorDezanneau, Guilhemcat
dc.contributor.authorCirera Hernández, Albertcat
dc.contributor.authorPeiró Martínez, Franciscacat
dc.contributor.authorCornet i Calveras, Albertcat
dc.contributor.authorMorante i Lleonart, Joan Ramoncat
dc.date.accessioned2012-05-03T07:46:49Z
dc.date.available2012-05-03T07:46:49Z
dc.date.issued2002-07-15
dc.description.abstractWe study the influence of Nb doping on the TiO2 anatase-to-rutile phase transition, using combined transmission electron microscopy, Raman spectroscopy, x-ray diffraction and selected area electron diffraction analysis. This approach enabled anatase-to-rutile phase transition hindering to be clearly observed for low Nb-doped TiO2 samples. Moreover, there was clear grain growth inhibition in the samples containing Nb. The use of high resolution transmission electron microscopy with our samples provides an innovative perspective compared with previous research on this issue. Our analysis shows that niobium is segregated from the anatase structure before and during the phase transformation, leading to the formation of NbO nanoclusters on the surface of the TiO2 rutile nanoparticles.eng
dc.format.extent9 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec500512
dc.identifier.issn0021-8979
dc.identifier.urihttps://hdl.handle.net/2445/24798
dc.language.isoengeng
dc.publisherAmerican Institute of Physics
dc.relation.isformatofReproducció del document publicat a: http://dx.doi.org/10.1063/1.1487915
dc.relation.ispartofJournal of Applied Physics, 2002, vol. 92, num. 2, p. 853- 861
dc.relation.urihttp://dx.doi.org/10.1063/1.1487915
dc.rights(c) American Institute of Physics, 2002
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Enginyeria Electrònica i Biomèdica)
dc.subject.classificationEquacions d'estatcat
dc.subject.classificationCiència dels materialscat
dc.subject.otherEquations of stateeng
dc.subject.otherMaterials scienceeng
dc.titleEffects of Nb doping on the TiO2 anatase-to-rutile phase transitioneng
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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