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Gas collisions and pressure quenching of the photoluminescence of silicon nanopowder grown by plasma-enhanced chemical vapor deposition
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The quenching of the photoluminescence of Si nanopowder grown by plasma-enhanced chemical vapor deposition due to pressure was measured for various gases ( H2, O2, N2, He, Ne, Ar, and Kr) and at different temperatures. The characteristic pressure, P0, of the general dependence I(P) = I0¿exp(¿P/P0) is gas and temperature dependent. However, when the number of gas collisions is taken as the variable instead of pressure, then the quenching is the same within a gas family (mono- or diatomic) and it is temperature independent. So it is concluded that the effect depends on the number of gas collisions irrespective of the nature of the gas or its temperature.
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ROURA GRABULOSA, Pere, COSTA I BALANZAT, Josep, MORANTE I LLEONART, Joan ramon, BERTRÁN SERRA, Enric. Gas collisions and pressure quenching of the photoluminescence of silicon nanopowder grown by plasma-enhanced chemical vapor deposition. _Journal of Applied Physics_. 1997. Vol. 81, núm. 7, pàgs. 3290-3293. [consulta: 8 de gener de 2026]. ISSN: 0021-8979. [Disponible a: https://hdl.handle.net/2445/24823]