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2016-11-28

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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/232239

Understanding the Thermodynamic Properties of the Elastocaloric Effect Through Experimentation and Modelling

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This paper presents direct and indirect methods for studying the elastocaloric effect (eCE) in shape memory materials and its comparison. The eCE can be characterized by the adiabatic temperature change or the isothermal entropy change (both as a function of applied stress/strain). To get these quantities, the evaluation of the eCE can be done using either direct methods, where one measures (adiabatic) temperature changes or indirect methods where one can measure the stress–strain–temperature characteristics of the materials and from these deduce the adiabatic temperature and isothermal entropy changes. The former can be done using the basic thermodynamic relations, i.e. Maxwell relation and Clausius–Clapeyron equation. This paper further presents basic thermodynamic properties of shape memory materials, such as the adiabatic temperature change, isothermal entropy change and total entropy–temperature diagrams (all as a function of temperature and applied stress/strain) of two groups of materials (Ni–Ti and Cu–Zn–Al alloys) obtained using indirect methods through phenomenological modelling and Maxwell relation. In the last part of the paper, the basic definition of the efficiency of the elastocaloric thermodynamic cycle (coefficient of performance) is defined and discussed.

Recurs relacionat

https://doi.org/10.1007/s40830-016-0094-8

Matèries

Aliatges, Propietats de la matèria, Elasticitat, Models matemàtics

Matèries (anglès)

Alloys, Properties of matter, Elasticity, Mathematical models

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Articles publicats en revistes (Física de la Matèria Condensada)

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TUSEK, J., et al. Understanding the Thermodynamic Properties of the Elastocaloric Effect Through Experimentation and Modelling. Shape Memory and Superelasticity. 2016. Vol. 2, num. 317-329. ISSN 2199-384X. [consulted: 2 of November of 2026]. Available at: https://hdl.handle.net/2445/232239

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