Stereoselective oxidation of titanium(IV) enolates with oxygen

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dc.contributor.authorGómez Palomino, Alejandro
dc.contributor.authorRomea, Pedro
dc.contributor.authorUrpí Tubella, Fèlix
dc.date.accessioned2019-02-12T10:48:08Z
dc.date.available2019-07-01T05:10:16Z
dc.date.issued2018-07-01
dc.date.updated2019-02-12T10:48:08Z
dc.description.abstractA novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A highly stereoselective oxidation of titanium(IV) enolates from chiral N-acyloxazolidinones is performed with oxygen under simple experimental conditions that do not require any reducing steps. The success of this approach depends on the biradical character of titanium(IV) enolates.
dc.format.extent6 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec681108
dc.identifier.issn0039-7881
dc.identifier.urihttps://hdl.handle.net/2445/128156
dc.language.isoeng
dc.publisherGeorg Thieme Verlag
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1055/s-0037-1609966
dc.relation.ispartofSynthesis. Journal of Synthetic Organic Chemistry, 2018, vol. 50, num. 14, p. 2721-2726
dc.relation.urihttps://doi.org/10.1055/s-0037-1609966
dc.rights(c) Georg Thieme Verlag, 2018
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationTitani
dc.subject.classificationEstereoquímica
dc.subject.classificationQuiralitat
dc.subject.otherTitanium
dc.subject.otherStereochemistry
dc.subject.otherChirality
dc.titleStereoselective oxidation of titanium(IV) enolates with oxygen
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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