Enantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophylline

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dc.contributor.authorAmat Tusón, Mercedes
dc.contributor.authorRamos, Carlos
dc.contributor.authorPérez Bosch, Maria
dc.contributor.authorMolins i Grau, Elies
dc.contributor.authorFlorindo, Pedro
dc.contributor.authorSantos, Maria M. M.
dc.contributor.authorBosch Cartes, Joan
dc.date.accessioned2013-04-30T10:52:01Z
dc.date.available2014-03-07T23:02:13Z
dc.date.issued2013-03-07
dc.date.updated2013-04-29T15:13:30Z
dc.description.abstractStarting from (S)-tryptophanol, a formal synthesis of ent-rhyncho-phylline and ent-isorhynchophylline, involving stereoselective cyclocondensation, spirocyclization, and alkylation reactions, and the final adjustment of the oxidation level at the oxindole and piperidine moieties, is reported.
dc.format.extent3 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec620577
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/2445/36425
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: http://dx.doi.org/10.1039/c2cc38540f
dc.relation.ispartofChemical Communications, 2013, vol. 49, num. 19, p. 1954-1956
dc.relation.urihttp://dx.doi.org/10.1039/c2cc38540f
dc.rights(c) Amat Tusón, Mercedes et al., 2013
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject.classificationAlcaloides
dc.subject.classificationSíntesi asimètrica
dc.subject.classificationEstereoquímica
dc.subject.otherAlkaloids
dc.subject.otherAsymmetric synthesis
dc.subject.otherStereochemistry
dc.titleEnantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophyllineeng
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)