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Three lanthanide complexes with mixed salicylate and 1,10-phenanthroline: syntheses, crystal structures, and luminescent/magnetic properties
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Three new lanthanide complexes incorporating salicylate (HSA or SA) and 1,10-phenanthroline (phen), Ln(3)(HSA)(5)(SA)(2)(phen)(3) [Ln=Ho (1) and Er (2)], and Sm-2(HSA)(2)(SA)(2)(phen)(3) (3), have been synthesized. X-ray structural analysis reveals that 1 and 2 are isostructural with a trinuclear pattern, and 3 exhibits a binuclear structure. Comparison of the structural differences between 1/2 and 3 suggests that the identity of metal plays an important role in construction of such complexes. The magnetic properties of 1 are discussed. Moreover, 2 and 3 are both photoluminescent materials, and their emission properties are closely related to their corresponding Ln(III) centers.
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HU, Min, YUE, Ling-yu, SAÑUDO ZOTES, Eva carolina, FANG, Shao-ming. Three lanthanide complexes with mixed salicylate and 1,10-phenanthroline: syntheses, crystal structures, and luminescent/magnetic properties. _Journal of Coordination Chemistry_. 2016. Vol. 69, núm. 14, pàgs. 2164-2173. [consulta: 25 de gener de 2026]. ISSN: 0095-8972. [Disponible a: https://hdl.handle.net/2445/154365]