Files
Document type
ArticleVersion
Accepted versionPublication date
All rights reserved
Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/195306
Aggregation of gold(I) complexes: phosphorescence vs. singlet oxygen production
Journal Title
Director/Tutor
Additional contribution
Journal ISSN
Volume Title
Abstract
Herein we report on the synthesis of six new phosphane-gold(I)-4-ethynylaniline complexes (neutral and cationic), with a tris-naphthalene substituted tertiary phosphane bearing a secondary amine as a linker and containing different halogen groups (Cl and Br) in the naphthyl group. We have demonstrated in this work how the careful control of the intermolecular aggregation process can modulate the competition between phosphorescence emission and energy transfer from the triplet state of the gold(I) complexes to produce singlet oxygen.
Related resource
Subject (English)
Citation
Citation
PINTO MARTÍNEZ, Andrea, et al. Aggregation of gold(I) complexes: phosphorescence vs. singlet oxygen production. Dalton Transactions. 2022. Vol. 51, num. 8795-8803. ISSN 1477-9226. [consulted: 8 of October of 2026]. Available at: https://hdl.handle.net/2445/195306