Exploiting Reaction-Diffusion Conditions to Trigger Pathway Complexity in the Growth of a MOF

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dc.contributor.authorCalvo Galve, Néstor
dc.contributor.authorAbrishamkar, Afshin
dc.contributor.authorSorrenti, Alessandro
dc.contributor.authorDi Rienzo, Lorenzo
dc.contributor.authorSatta, Mauro
dc.contributor.authorD'Abramo, Marco
dc.contributor.authorCoronado, Eugenio
dc.contributor.authorDe Mello, Andrew J.
dc.contributor.authorMínguez Espallargas, Guillem
dc.contributor.authorPuigmartí-Luis, Josep
dc.date.accessioned2022-04-26T15:05:39Z
dc.date.available2022-04-26T15:05:39Z
dc.date.issued2021-07-12
dc.date.updated2022-04-26T15:05:39Z
dc.description.abstractCoordinationpolymers(CPs),includingmetal-organicframeworks(MOFs),are crystallinematerialswithpromisingapplicationsin electronics,magnetism,catalysis,andgas storage/separation.However,the mechanismsandpath-waysunderlyingtheirformationremainlargelyundisclosed.Herein,we demonstratethatdiffusion-controlledmixingofreagentsat the veryearlystagesof the crystallizationprocess(i.e., within 40 ms),achievedby usingcontinuous-flowmicrofluidicdevices,can be usedto enablenovelcrystallizationpathwaysofaprototypicalspin-crossover MOFtowards itsthermodynamicproduct.In particular,twodistinctandunprecedentednucleation-growth pathwayswere experimen-tallyobservedwhencrystallizationwas triggeredundermicro-fluidicmixing.Full-atommoleculardynamicssimulationsalsoconfirmthe occurrenceof thesetwo distinctpathwaysduringcrystalgrowth.In sharpcontrast,acrystallizationby particleattachmentwas observedunderbulk(turbulent)mixing.Theseunprecedentedresultsprovideasoundbasisfor understandingthe growth of CPsand openup newavenuesfor the engineer-ing of porousmaterialsby usingout-of-equilibriumconditions
dc.format.extent8 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec719750
dc.identifier.issn1433-7851
dc.identifier.urihttps://hdl.handle.net/2445/185127
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1002/anie.202101611
dc.relation.ispartofAngewandte Chemie-International Edition, 2021, vol. 60, num. 29, p. 15920-15927
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/677020/EU//microCrysFact
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/724681/EU//S-CAGE
dc.relation.urihttps://doi.org/10.1002/anie.202101611
dc.rightscc-by-nc (c) Calvo Galve, Néstor, et al., 2021
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/es/*
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationPolímers
dc.subject.classificationCristal·lització
dc.subject.classificationMicrofluídica
dc.subject.otherPolymers
dc.subject.otherCrystallization
dc.subject.otherMicrofluidics
dc.titleExploiting Reaction-Diffusion Conditions to Trigger Pathway Complexity in the Growth of a MOF
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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