Synthesis and study of the luminescent properties of gold(I) organometallic complexes

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dc.contributor.advisorAngurell Purroy, Inmaculada
dc.contributor.authorSevillano Santamaria, Alba
dc.date.accessioned2023-03-10T16:10:15Z
dc.date.available2025-01-31T06:10:11Z
dc.date.issued2023-01
dc.descriptionTreballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2023, Tutora: Inmaculada Angurell Purroyca
dc.description.abstractThe study of gold-(I) organometallic complexes has been of great interest over the last few years due to their luminescent properties. These compounds have a wide range of applications in different research fields such as chemosensors, photodynamic therapy and optical limiting. In this project, several mono- and dinuclear gold-(I) complexes have been synthesized. These linear complexes contain a triphenylene ligand with alkynyl moieties at the first coordination position of gold atom and a phosphane at the second coordination position. Several monophosphanes (-PTA, -PPh3, -PMe3) and diphosphanes (-dppe, -dppm, -xantphos and -spanphos) have been used to obtain gold complexes with different properties. 1H NMR, 31P-{H} NMR, IR, ESI-MS(+) techniques have been used to characterize the products and confirm the successful formation of gold-(I) derivatives. Lastly, the luminescent properties of the gold-(I) complexes have been studied recording the absorption and emission spectraca
dc.format.extent59 p.
dc.format.mimetypeapplication/pdf
dc.identifier.urihttps://hdl.handle.net/2445/195038
dc.language.isoengca
dc.rightscc-by-nc-nd (c) Sevillano, 2023
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/es/*
dc.sourceTreballs Finals de Grau (TFG) - Química
dc.subject.classificationCromòforcat
dc.subject.classificationAlquinilcat
dc.subject.classificationLuminescènciacat
dc.subject.classificationTreballs de fi de graucat
dc.subject.otherChromophoreeng
dc.subject.otherAlkynyleng
dc.subject.otherLuminescenceeng
dc.subject.otherBachelor's theses
dc.titleSynthesis and study of the luminescent properties of gold(I) organometallic complexeseng
dc.title.alternativeSíntesi i estudi de les propietats luminescents de complexos organometal·lics d’or(I)ca
dc.typeinfo:eu-repo/semantics/bachelorThesisca

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Treballs Finals de Grau (TFG) - Química