Mirror symmetry breaking with limited enantioselective autocatalysis and temperature gradients: a stability survey

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dc.contributor.authorBlanco, Celia
dc.contributor.authorRibó i Trujillo, Josep M.
dc.contributor.authorCrusats i Aliguer, Joaquim
dc.contributor.authorEl Hachemi, Zoubir
dc.contributor.authorMoyano i Baldoire, Albert
dc.date.accessioned2020-05-14T10:23:51Z
dc.date.available2020-05-14T10:23:51Z
dc.date.issued2013-03-07
dc.date.updated2020-05-14T10:23:52Z
dc.description.abstractWe analyze limited enantioselective (LES) autocatalysis in a temperature gradient and with internal flow/recycling of hot and cold material. Microreversibility forbids broken mirror symmetry for LES in the presence of a temperature gradient alone. This symmetry can be broken however when the auto-catalysis and limited enantioselective catalysis are each localized within the regions of low and high temperature, respectively. This scheme has been recently proposed as a plausible model for spontaneous emergence of chirality in abyssal hydrothermal vents. Regions in chemical parameter space are mapped out in which the racemic state is unstable and bifurcates to chiral solutions.
dc.format.extent11 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec622795
dc.identifier.issn1463-9076
dc.identifier.urihttps://hdl.handle.net/2445/160238
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c2cp43488a
dc.relation.ispartofPhysical Chemistry Chemical Physics, 2013, vol. 15, num. 5, p. 1546-1556
dc.relation.urihttps://doi.org/10.1039/c2cp43488a
dc.rights(c) Blanco, Celia et al., 2013
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationQuiralitat
dc.subject.classificationDicroisme circular
dc.subject.classificationCatàlisi
dc.subject.classificationEnantiòmers
dc.subject.otherChirality
dc.subject.otherCircular dichroism
dc.subject.otherCatalysis
dc.subject.otherEnantiomers
dc.titleMirror symmetry breaking with limited enantioselective autocatalysis and temperature gradients: a stability survey
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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