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2019-09-10

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/154186

Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies

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https://doi.org/10.1002/chem.201903829

Abstract

The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities

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Terres rares, Imants, Compostos de coordinació

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Rare earths, Magnets, Coordination compounds

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Articles publicats en revistes (Química Inorgànica i Orgànica)

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VELASCO AMIGÓ, Verónica, et al. Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies. Chemistry-A European Journal. 2019. Vol. 25, num. 67, pags. 15228-15232. ISSN 0947-6539. [consulted: 18 of June of 2026]. Available at: https://hdl.handle.net/2445/154186

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