Increasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited state

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dc.contributor.authorOyarzabal, I.
dc.contributor.authorRuiz Dueñas, J.
dc.contributor.authorRuiz Sabín, Eliseo
dc.contributor.authorAravena Ponce, Daniel Alejandro
dc.contributor.authorSeco, J. M.
dc.contributor.authorColacio, Enrique
dc.date.accessioned2020-03-31T15:22:20Z
dc.date.available2020-03-31T15:22:20Z
dc.date.issued2015-06-17
dc.date.updated2020-03-31T15:22:21Z
dc.description.abstractThe trinuclear complex [ZnCl(l-L)Dy(l-L)ClZn]PF6 exhibits a single- molecule magnetic behaviour under zero field with a relatively large effective energy barrier of 186 cm􏰁1. Ab initio calculations reveal that the relaxation of the magnetization is symmetry-driven (the DyIII ion possesses a C2 symmetry) and occurs via the second excited state.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec656357
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/2445/154553
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/c5cc04495b
dc.relation.ispartofChemical Communications, 2015, vol. 51, num. 62, p. 12353-12356
dc.relation.urihttps://doi.org/10.1039/c5cc04495b
dc.rights(c) Oyarzabal, I. et al., 2015
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationMagnetisme
dc.subject.classificationIons metàl·lics
dc.subject.otherMagnetism
dc.subject.otherMetal ions
dc.titleIncreasing the effective energy barrier promoted by the change of a counteranion in a Zn-Dy-Zn SMM: slow relaxation via the second excited state
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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