Metastability in supersaturated solution and transition towards chirality in the crystallization of NaClO3

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dc.contributor.authorEl Hachemi, Zoubir
dc.contributor.authorCrusats i Aliguer, Joaquim
dc.contributor.authorRibó i Trujillo, Josep M.
dc.contributor.authorMcBride, J. Michael
dc.contributor.authorVeintemillas Verdaguer, Sabino
dc.date.accessioned2023-03-22T10:07:17Z
dc.date.available2023-03-22T10:07:17Z
dc.date.issued2011-02-04
dc.date.updated2023-03-22T10:07:17Z
dc.description.abstractAnalysis of the chiral composition of the crystal mixture obtained from samples of boiling solutions of NaClO3 (see picture) indicates that symmetry breaking towards homochiral compositions may begin in the metastable stage preceding crystallization, that is, at the level of subcritical clusters.
dc.format.extent5 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec595009
dc.identifier.issn1433-7851
dc.identifier.urihttps://hdl.handle.net/2445/195763
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/anie.201007209
dc.relation.ispartofAngewandte Chemie-International Edition, 2011, vol. 50, num. 10, p. 2359-2363
dc.relation.urihttps://doi.org/10.1002/anie.201007209
dc.rights(c) Wiley-VCH, 2011
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationQuiralitat
dc.subject.classificationCreixement cristal·lí
dc.subject.otherChirality
dc.subject.otherCrystal growth
dc.titleMetastability in supersaturated solution and transition towards chirality in the crystallization of NaClO3
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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