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Article

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Accepted version

Publication date

2015-07-29

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/154598

A trinuclear CuII complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment

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https://doi.org/10.1039/c5dt02485d

Abstract

A new kind of N-ligands based on heptazine derivatives is presented. A trinuclear CuII complex, [(L)2CuII3Cl3](ClO4)3·3CH2Cl2 (L=2,5,8-tris-(di-2-pyrildylamine) heptazine), utilizing a pyridine derivative of heptazine has been synthesized and characterized avoiding the inherent solubility problems of heptazine compounds. Thus, this work opens the application of such ligands either in supramolecular chemistry as a larger ligand of the widely used s-triazine derivatives or to provide molecular systems for photocatalysis as heptazine is the fundamental unit of the very promising g-C3N4 2D compound.

Subject

Fotocatàlisi, Química supramolecular

Subject (English)

Photocatalysis, Supramolecular chemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

MAXWELL VILLACORTA, Lindley Andrés, et al. A trinuclear CuII complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment. Dalton Transactions. 2015. Vol. 44, num. 36, pags. 15761-15763. ISSN 1477-9226. [consulted: 12 of June of 2026]. Available at: https://hdl.handle.net/2445/154598

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