First enantioselective synthesis of isagarin, a natural product isolated from Pentas longiflora Oliv.

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dc.contributor.authorJacobs, Jan
dc.contributor.authorClaessens, Sven
dc.contributor.authorMol, Eva de
dc.contributor.authorEl Hady, Samir
dc.contributor.authorMinguillón Llombart, Cristina
dc.contributor.authorÁlvarez Domingo, Mercedes
dc.contributor.authorKimpe, Norbert de
dc.date.accessioned2014-06-13T10:16:28Z
dc.date.available2014-06-13T10:16:28Z
dc.date.issued2010-04-30
dc.date.updated2014-06-13T10:16:28Z
dc.description.abstractFor the first time, an enantioselective synthesis of both 1R,4S-isagarin 1a and 1S,4R-isagarin 1b was achieved starting from 1,4-dimethoxy-2-vinylnaphtalene 2. The key steps involve a Sharpless asymmetric dihydroxylation and reaction with an acetonylating pyridinium ylid.
dc.format.extent3 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec585961
dc.identifier.issn0040-4020
dc.identifier.urihttps://hdl.handle.net/2445/54980
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.isformatofVersió postprint del document publicat a: http://dx.doi.org/10.1016/j.tet.2010.04.105
dc.relation.ispartofTetrahedron, 2010, vol. 66, num. 27-28, p. 5158-5160
dc.relation.urihttp://dx.doi.org/10.1016/j.tet.2010.04.105
dc.rights(c) Elsevier B.V., 2010
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject.classificationSíntesi asimètrica
dc.subject.classificationProductes naturals
dc.subject.otherAsymmetric synthesis
dc.subject.otherNatural products
dc.titleFirst enantioselective synthesis of isagarin, a natural product isolated from Pentas longiflora Oliv.
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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