A magneto-optical molecular device: interplay of spin crossover, luminescence, photomagnetism, and photochromism

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dc.contributor.authorEstrader i Bofarull, Marta
dc.contributor.authorSalinas Uber, Jorge
dc.contributor.authorBarrios Moreno, Leoní Alejandra
dc.contributor.authorGarcía Gómez, Jordi
dc.contributor.authorLloyd-Williams, Paul
dc.contributor.authorRoubeau, Olivier
dc.contributor.authorTeat, Simon J.
dc.contributor.authorAromí Bedmar, Guillem
dc.date.accessioned2020-03-25T08:14:50Z
dc.date.available2020-03-25T08:14:50Z
dc.date.issued2017-12-04
dc.date.updated2020-03-25T08:14:50Z
dc.description.abstractA bis(pyrazolylpyridyl) ligand, L, containing a cen- tral photochromic dithienylethene spacer predictably forms a ferrous [Fe2L3]4+ helicate exhibiting spin crossover (SCO). In solution, the compound [Fe2L3](ClO4)4 (1) preserves the magnetic properties and is fluorescent. The structure of 1 is photo-switchable following the reversible ring closure/opening of the central dithienylethene via irradiation with UV/visible light. This photoisomerization switches on and off some emission bands of 1 and provides a means of externally manipulating the magnetic properties of the assembly.
dc.format.extent6 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec674471
dc.identifier.issn1433-7851
dc.identifier.urihttps://hdl.handle.net/2445/153717
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1002/anie.201709136
dc.relation.ispartofAngewandte Chemie-International Edition, 2017, vol. 56, num. 49, p. 15622-15627
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/258060/EU//FUNCMOLQIP
dc.relation.urihttps://doi.org/10.1002/anie.201709136
dc.rights(c) Wiley-VCH, 2017
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationFluorescència
dc.subject.classificationFotoquímica
dc.subject.classificationPropietats magnètiques
dc.subject.otherFluorescence
dc.subject.otherPhotochemistry
dc.subject.otherMagnetic properties
dc.titleA magneto-optical molecular device: interplay of spin crossover, luminescence, photomagnetism, and photochromism
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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