Novel PTM-TEMPO biracial for fast dissolution dynamic nuclear polarization

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dc.contributor.authorMuñoz-Gómez, José Luis
dc.contributor.authorMarín Montesinos, Ildefonso
dc.contributor.authorLoveras, Vega
dc.contributor.authorPons Vallès, Miquel
dc.contributor.authorVidal-Gancedo, José
dc.contributor.authorVeciana, Jaume
dc.date.accessioned2018-09-26T11:20:00Z
dc.date.available2018-09-26T11:20:00Z
dc.date.issued2014-10-03
dc.date.updated2018-09-26T11:20:01Z
dc.description.abstractThe synthesis and characterization of a novel trityl-TEMPO biradical and the investigation of its properties as Dynamic Nuclear Polarization (DNP) polarizing agent are reported. Comparison with a structurally related monoradical (PTM-TEMPE) or mixtures of the two monoradical components reveals that the biradical has a much higher polarization efficiency and a faster polarization buildup. This offers the possibility of faster recycling further contributing to its efficiency as a polarizing agent.
dc.format.extent4 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec644145
dc.identifier.issn1523-7060
dc.identifier.urihttps://hdl.handle.net/2445/124832
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/ol502644x
dc.relation.ispartofOrganic Letters, 2014, vol. 16, num. 20, p. 5402-5405
dc.relation.urihttps://doi.org/10.1021/ol502644x
dc.rights(c) American Chemical Society , 2014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationPolarització (Física nuclear)
dc.subject.otherPolarization (Nuclear physics)
dc.titleNovel PTM-TEMPO biracial for fast dissolution dynamic nuclear polarization
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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