Supramolecular sensing with luminescent gold(I) and platinum (II) organometallics

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dc.contributor.authorLázaro Palacios, Ariadna
dc.contributor.authorPinto Martínez, Andrea
dc.contributor.authorRodríguez Raurell, Laura
dc.date.accessioned2026-09-17T11:25:25Z
dc.date.available2026-09-17T11:25:25Z
dc.date.issued2026-03-01
dc.date.updated2026-09-17T11:25:26Z
dc.description.abstractLuminescent chemosensors based on supramolecular principles provide sensitive, non-invasive detection of diverse analytes. Among non-covalent interactions, metallophilic forces, weak attractions between closed-shell metal centers, have proven effective in tuning photophysical properties. This review highlights recent advances in gold (I) and platinum(II) chemosensors, where Au(I)···Au(I) and Pt(II)···Pt(II) contacts govern sensing. Analyte binding modulates metal–metal proximity, switching luminescence via unique emissive states such as MMLCT. These interactions also drive aggregation-induced emission (AIE), vapochromism, and excimer-like emission. Applications include detecting heavy metals, anions, VOCs, PAHs, and biorelevant molecules. Overall, leveraging metallophilic interactions offers a versatile strategy for designing advanced luminescent sensors.
dc.format.extent18 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec764810
dc.identifier.issn0010-8545
dc.identifier.urihttps://hdl.handle.net/2445/231536
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.ccr.2025.217411
dc.relation.ispartofCoordination Chemistry Reviews, 2026, vol. 550
dc.relation.urihttps://doi.org/10.1016/j.ccr.2025.217411
dc.rightscc-by-nc-nd (c) Elsevier B.V., 2026
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationCompostos d'or
dc.subject.classificationEspectroscòpia de fluorescència
dc.subject.otherGold compounds
dc.subject.otherFluorescence spectroscopy
dc.titleSupramolecular sensing with luminescent gold(I) and platinum (II) organometallics
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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