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L22_2018_Chemical Communications_54_4112_OA.pdf (1.46 MB)

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Article

Data de publicació

2018-03-27

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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/127393

From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design

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Recurs relacionat

https://doi.org/10.1039/C8CC01259H

Resum

Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).

Matèries

Polimerització, Estructura molecular, Aigua

Matèries (anglès)

Polymerization, Molecular structure, Water

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Articles publicats en revistes (Institut de Bioenginyeria de Catalunya (IBEC))

Citació

CASELLAS, Nicolas M., et al. From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design. Chemical Communications. 2018. Vol. 54, num. 33, pags. 4112-4115. [consulted: 7 of July of 2026]. Available at: https://hdl.handle.net/2445/127393

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