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2018-03-27

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/127393

From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design

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Abstract

Two structurally-similar discotic molecules able to self-assemble in water, forming supramolecular fibers, are reported. While both self-assembled polymers are indistinguishable from a morphological point-of-view, a dramatic change in their polymerization mechanism is observed (i.e., one self-assemble via an isodesmic mechanism, while the other shows one of the highest cooperativity values).

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https://doi.org/10.1039/C8CC01259H

Subject

Polimerització, Estructura molecular, Aigua

Subject (English)

Polymerization, Molecular structure, Water

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Articles publicats en revistes (Institut de Bioenginyeria de Catalunya (IBEC))

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CASELLAS, Nicolas M., et al. From isodesmic to highly cooperative: Reverting the supramolecular polymerization mechanism in water by fine monomer design. Chemical Communications. 2018. Vol. 54, num. 33, pags. 4112-4115. [consulted: 16 of October of 2026]. Available at: https://hdl.handle.net/2445/127393

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