Coordination [CoII2] and [CoIIZnII] helicates showing slow magnetic relaxation

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dc.contributor.authorDiego, Rosa
dc.contributor.authorPavlov, Alexander
dc.contributor.authorDarawsheh, Mohanad D.
dc.contributor.authorAleshin, Dmitry
dc.contributor.authorNehrkorn, Joscha
dc.contributor.authorNelyubina, Yulia
dc.contributor.authorRoubeau, Olivier
dc.contributor.authorNovikov, Valentin
dc.contributor.authorAromí Bedmar, Guillem
dc.date.accessioned2019-10-17T13:13:28Z
dc.date.available2020-07-08T05:10:23Z
dc.date.issued2019-07-08
dc.date.updated2019-10-17T13:13:28Z
dc.description.abstractThe slow magnetic relaxation of CoII ions in the elusive intermediate geometry between the trigonal prism and antiprism has been studied on the new [Co2L3]4+ and [CoZnL3]4+ coordination helicates [L is a bis(pyrazolylpyridine) ligand]. Solution paramagnetic 1H NMR and solid-state magnetization measurements unveil single-molecule-magnet behavior with small axial anisotropy, as predicted previously.
dc.format.extent5 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec692135
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/2445/142544
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.9b01334
dc.relation.ispartofInorganic Chemistry, 2019, vol. 58, num. 15, p. 9562-9566
dc.relation.urihttps://doi.org/10.1021/acs.inorgchem.9b01334
dc.rights(c) American Chemical Society , 2019
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationMolècules
dc.subject.classificationPropietats magnètiques
dc.subject.otherMolecules
dc.subject.otherMagnetic properties
dc.titleCoordination [CoII2] and [CoIIZnII] helicates showing slow magnetic relaxation
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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