Facile synthesis of azocino[4,3-b]indoles by ring-closing metathesis

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dc.contributor.authorBennasar Fèlix, M. Lluïsa
dc.contributor.authorZulaica Gallego, Ester
dc.contributor.authorSolé Arjó, Daniel
dc.contributor.authorAlonso Serrano, Sandra
dc.date.accessioned2020-05-15T09:12:08Z
dc.date.available2020-05-15T09:12:08Z
dc.date.issued2007-01
dc.date.updated2020-05-15T09:12:08Z
dc.description.abstractThe azocino[4,3-b]indole system, tricyclic substructure of the indole alkaloids apparicine and ervaticine, is efficiently assembled by ring-closing metathesis of 2-allyl-3-(allylaminomethyl)indoles. The metathesis sites are introduced into the indole nucleus by reductive amination of a 3-formyl derivative with allylamine, followed by a-lithiation with subsequent electrophilic trapping with acrolein.
dc.format.extent6 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec555923
dc.identifier.issn0040-4020
dc.identifier.urihttps://hdl.handle.net/2445/160425
dc.language.isoeng
dc.publisherElsevier B.V.
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1016/j.tet.2006.11.043
dc.relation.ispartofTetrahedron, 2007, vol. 63, num. 4, p. 861-866
dc.relation.urihttps://doi.org/10.1016/j.tet.2006.11.043
dc.rights(c) Elsevier B.V., 2007
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject.classificationAlcaloides
dc.subject.classificationMetàtesi (Química)
dc.subject.classificationSíntesi orgànica
dc.subject.otherAlkaloids
dc.subject.otherMetathesis (Chemistry)
dc.subject.otherOrganic synthesis
dc.titleFacile synthesis of azocino[4,3-b]indoles by ring-closing metathesis
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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