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Two isostructural coordination polymers showing diverse magnetic behaviors: weak coupling (NiII) and an ordered array of single-chain magnets (CoII)

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Two isomorphic 3-D complexes with the formulas [M3(TPTA) (OH)2(H2O)4]n (M = Ni for 1 and Co for 2; H4TPTA = [1,1′:4′,1″-terphenyl]-2′,3,3″,5′-tetracarboxylic acid) have been synthesized and magnetically characterized. Complexes 1 (NiII) and 2 (CoII) have the same 1-D rod-shaped inorganic SBUs but exhibit significantly different magnetic properties. Complex 2(CoII) is a 3-D arrangement of a 1-D CoII single-chain magnet (SCM), while complex 1(NiII) exhibits weak coupling

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CHEN, Min, et al. Two isostructural coordination polymers showing diverse magnetic behaviors: weak coupling (NiII) and an ordered array of single-chain magnets (CoII). Inorganic Chemistry. 2016. Vol. 55, num. 8, pags. 3715-3717. ISSN 0020-1669. [consulted: 22 of May of 2026]. Available at: https://hdl.handle.net/2445/154178

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