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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/152750
Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes
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The synthesis of two dinuclear ionic complexes with chemical formula [Au(PR3)2][Au(C≡CC5H4N)2] that contain the water soluble phosphines, PR3, PTA (1, 3,5-triaza-7-phosphaadamantane, 1) and DAPTA (3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane, 2) is herein described. The differences on their intermolecular reorganization have been analyzed and compared with the previously reported for the neutral complexes [Au(PR3)(C≡CC5H4N)]. It has been evidenced that the reorganization of the ligands giving rise to the dinuclear ionic complexes produces a complete change in the properties giving rise to Au***Au intermolecular assemblies. These aurophilic contacts are the responsible for the resulting luminescence which is not displayed for the parent compounds [Au(PR3)2]Cl and [PPh4][Au(C≡CC5H4N)2]. Compounds 1 and 2 were made react with three different silver salts (nitrate, triflate and hexafluorophosphate) giving rise to 1:1 heterometallic assemblies with some changes both on the wavelength and emission intensity.
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SVAHN, Noora, SANZ BEGUER, Ingrid, RISSANEN, Kari, RODRÍGUEZ RAURELL, Laura. Supramolecular assemblies and photophysical properties of ionic homo- and heteronuclear metallophilic complexes. _Journal of Organometallic Chemistry_. 2019. Vol. 897, núm. 170-177. [consulta: 22 de gener de 2026]. ISSN: 0022-328X. [Disponible a: https://hdl.handle.net/2445/152750]