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Microwave assisted synthesis of heterometallic 3d-4f M4Ln complexes

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dc.contributor.authorRosado Piquer, Lidia
dc.contributor.authorDey, S.
dc.contributor.authorTeat, Simon J.
dc.contributor.authorCirera Fernández, Jordi
dc.contributor.authorRajaraman, Gopalan
dc.contributor.authorSañudo Zotes, Eva Carolina
dc.date.accessioned2019-09-06T08:23:46Z
dc.date.available2020-08-19T05:10:26Z
dc.date.issued2019-08-19
dc.date.updated2019-09-06T08:23:47Z
dc.description.abstractIn this paper we describe the synthesis and magnetic properties of a series of 3d-4f complexes of general formula [M4Ln(OH)2(chp)4(SALOH)5(H2O)(MeCN)(Solv)] (Solv = MeOH, MeCN, H2O; chp stands for deprotonated 6-chloro-2-hydroxypyridine (C5H3ClNO), SALOH stands for monodeprotonated 3,5-ditert-butylsalicylic acid (C15H21O3)) obtained by a solvent-free microwave assisted synthesis method. The Ni(II) complexes (Ni4Gd, Solv = MeOH; Ni4Dy, Solv = MeCN) are not SMMs in the absence of an applied dc field. The replacement of Ni(II) by Co(II) (Co4La, Solv = MeOH; Co4Gd, Solv = H2O; Co4Gd-MeCN, Solv = MeCN; Co4Tb, Solv = MeOH; Co4Dy, Solv = H2O) results in improved SMM properties.
dc.format.extent11 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec691144
dc.identifier.issn1477-9226
dc.identifier.urihttps://hdl.handle.net/2445/139424
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1039/C9DT02567G
dc.relation.ispartofDalton Transactions, 2019, vol. 48, p. 12440-12450
dc.relation.urihttps://doi.org/10.1039/C9DT02567G
dc.rights(c) Rosado Piquer, Lidia et al., 2019
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationCompostos metàl·lics
dc.subject.classificationPropietats magnètiques
dc.subject.otherMetallic composites
dc.subject.otherMagnetic properties
dc.titleMicrowave assisted synthesis of heterometallic 3d-4f M4Ln complexes
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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