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Molecular prototypes for spin-based CNOT and SWAP quantum gates
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We show that a chemically engineered structural asymmetry in [Tb2] molecular clusters renders the two weakly coupled Tb3+ spin qubits magnetically inequivalent. The magnetic energy level spectrum of these molecules meets then all conditions needed to realize a universal CNOT quantum gate. A proposal to realize a SWAP gate within the same molecule is also discussed. Electronic paramagnetic resonance experiments confirm that CNOT and SWAP transitions are not forbidden.
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AROMÍ BEDMAR, Guillem, et al. Molecular prototypes for spin-based CNOT and SWAP quantum gates. Physical Review Letters. 2011. Vol. 107, num. 11, pags. 117203(5). ISSN 0031-9007. [consulted: 8 of June of 2026]. Available at: https://hdl.handle.net/2445/24623