Fitxers
Tipus de document
ArticleVersió
Versió publicadaData de publicació
Tots els drets reservats
Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/173121
Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
Títol de la revista
Director/Tutor
ISSN de la revista
Títol del volum
Recurs relacionat
Resum
The action of Pd(AcO)2 on imines derived from (R)-1-phenylethylamine, R1CR:NCHMePh, [R1 = 4-ClC6H4, R = H (1); R1 = 3,5-F2C6H3, R = H (2) and R1 = C6H5, R = Me (3)] and subsequent treatment with LiBr gives the corresponding optically active cyclopalladated dimers I. In all cases the endocyclic derivs. were formed selectively, even with the imine 2, which contains fluoro substituents on the C atom adjacent to the metalation position. The action of PPh3 on the bromo bridged compds. I affords mononuclear II.
Matèries (anglès)
Citació
Citació
ALBERT MACH, Joan, GRANELL SANVICENTE, Jaime Ramón and MÍNGUEZ, Jorge. Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines. Anales de Quimica. 1996. Vol. 92, num. 396-399. ISSN 1575-3417. [consulted: 27 of May of 2026]. Available at: https://hdl.handle.net/2445/173121