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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/220482
On-surface magnetocaloric effect for a Van der Waals Gd(III) 2D MOF grown on Si
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Gd complexes have been studied as magnetic coolants due to their large magneto-caloric effect. In this work we present a Gd 2D metal–organic framework (MOF) of formula [Gd(MeCOO)(PhCOO)2] (1). We characterize the magnetic properties of 1, showing that it displays slow relaxation of the magnetization by ac susceptibility, and single-ion magnetic anisotropy using high-field EPR. By heat capacity and magnetization vs. field at various temperatures we determine the magnetic entropy change of compound 1. We then grow 1 on functionalized silicon, and show that the surface-deposited 2D MOF 1Si can be used as an on-surface magnetic cryogenic coolant.
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HILL, Stephen, et al. On-surface magnetocaloric effect for a Van der Waals Gd(III) 2D MOF grown on Si. Journal of Materials Chemistry A. 2024. Vol. 1-12. ISSN 2050-7488. [consulted: 7 of October of 2026]. Available at: https://hdl.handle.net/2445/220482