Toward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs

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dc.contributor.authorTarushi, Alketa
dc.contributor.authorHatzidimitriou, Antonios G.
dc.contributor.authorEstrader i Bofarull, Marta
dc.contributor.authorKessissoglou, Dimitris P.
dc.contributor.authorTangoulis, Vassilis
dc.contributor.authorPsomas, George
dc.date.accessioned2021-03-31T15:23:28Z
dc.date.available2021-03-31T15:23:28Z
dc.date.issued2017-06-07
dc.date.updated2021-03-31T15:23:28Z
dc.description.abstractThe interaction of Mn(ClO4)2·6H2O with salicylaldoxime (H2sao) in the presence of nonsteroidal anti-inflammatory drug (NSAID) sodium diclofenac (Nadicl) or indomethacin (Hindo) leads to the formation of the hexanuclear Mn(III) clusters [Mn6(O)2(dicl)2(sao)6(CH3OH)6] (1) and [Mn6(O)2(indo)2(sao)6(H2O)4] (2) both characterized as stepladder inverse-9-metallacrown-3 accommodating dicl- or indo- ligands, respectively. When the interaction of MnCl2·4H2O with Nadicl or Hindo is in the absence of H2sao, the mononuclear Mn(II) complexes [Mn(dicl)2(CH3OH)4] (3) and [Mn(indo)2(CH3OH)4] (4) were isolated. The complexes were characterized by physicochemical and spectroscopic techniques, and the structure of complexes 1 and 2 was characterized by X-ray crystallography. Magnetic measurements (dc and ac) were carried out in order to investigate the nature of magnetic interactions between the magnetic ions and the overall magnetic behavior of the complexes.
dc.format.extent10 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec675371
dc.identifier.issn0020-1669
dc.identifier.urihttps://hdl.handle.net/2445/175936
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.inorgchem.7b00655
dc.relation.ispartofInorganic Chemistry, 2017, vol. 56, num. 12, p. 7048-7057
dc.relation.urihttps://doi.org/10.1021/acs.inorgchem.7b00655
dc.rights(c) American Chemical Society , 2017
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationManganès
dc.subject.classificationAgents antiinflamatoris
dc.subject.classificationCompostos complexos
dc.subject.otherManganese
dc.subject.otherAntiinflammatory agents
dc.subject.otherComplex compounds
dc.titleToward multifunctional materials incorporating stepladder manganese(III) inverse-[9-MC-3]-Metallacrowns and anti-inflammatory drugs
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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