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2016-12-05

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Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/153838

Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br- or I-)

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https://doi.org/10.1039/c6cc08906b

Abstract

Ligand 1,3-bis(3-(pyridin-2-yl)-1H-pyrazol-5-yl) benzene, L, forms mononuclear spin crossover complexes [FeL3](2+) with pendant arms that cause them to dimerize through numerous intermolecular interactions forming supramolecular (X@[FeL3](3+) cations. They have the flexibility to encapsulate Cl-, Br- or I-), which allow tuning the magnetic properties, in the solid state and in solution.

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Ferro, Lligands, Química supramolecular

Subject (English)

Iron, Ligands, Supramolecular chemistry

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Articles publicats en revistes (Química Inorgànica i Orgànica)

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DARAWSHEH, Mohanad D., et al. Guest-tuned spin crossover in flexible supramolecular assemblies templated by a halide (Cl-, Br- or I-). Chemical Communications. 2016. Vol. 53, num. 3, pags. 569-572. ISSN 1359-7345. [consulted: 6 of June of 2026]. Available at: https://hdl.handle.net/2445/153838

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