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Si us plau utilitzeu sempre aquest identificador per citar o enllaçar aquest document: https://hdl.handle.net/2445/225366
Modulated spin dynamics of [Co_2] coordination helicates via differential strand composition
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Coordination supramolecular chemistry provides a versatile entry into materials with functionalities of technological relevance at the nanoscale. Here, we describe how two different bis-pyrazolylpyridine ligands (L1 and L2) assemble with Co(II ) ions into dinuclear triple-stranded helicates, in turn, encapsulating different anionic guests. These constructs are described as (Cl@[Co2 (L1)3])3+ , (SiF6 @[Co 2(L1)(L2)3])2+ and (ClO4 @[Co 2(L2)3 ])3+
, as established by single-crystal X-ray diffraction. Extensive magnetic and calorimetric
measurements, numerical treatments and theoretical calculations reveal that the individual Co(II) centers of these supramolecular entities exhibit field-induced slow relaxation of magnetization, dominated by direct and Raman mechanisms. While the small variations in the spin dynamics are not easily correlated with the evident structural differences among the three species, the specific heat measurements suggest two vibronic pathways of magnetic relaxation: one that would be associated with the host lattice and another linked with the guest.
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BARRIOS MORENO, Leoní alejandra, CAPÓ SERRANO, Núria, BOULEHJOUR, Hanae, RETA MAÑERU, Daniel, TEJEDOR RAMOS, Inés, ROUBEAU, Olivier, AROMÍ BEDMAR, Guillem. Modulated spin dynamics of [Co_2] coordination helicates via differential strand composition. _Dalton Transactions_. 2024. Vol. 53, núm. 17, pàgs. 7611-7618. [consulta: 29 de gener de 2026]. ISSN: 1477-9226. [Disponible a: https://hdl.handle.net/2445/225366]