Gas adsorption, magnetism, and single-crystal to single-crystal transformation studies of a three-dimensional Mn(II) porous coordination polymer

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dc.contributor.authorAgarwal, Rashmi A.
dc.contributor.authorMukherjee, Soumya
dc.contributor.authorSañudo Zotes, Eva Carolina
dc.contributor.authorGhosh, Sujit K
dc.contributor.authorBharadwaj, Parimal K
dc.date.accessioned2020-03-27T07:28:27Z
dc.date.available2020-03-27T07:28:27Z
dc.date.issued2014-10-21
dc.date.updated2020-03-27T07:28:27Z
dc.description.abstractA porous coordination polymer {[Mn2(DBIBA)3]×(NO3)·3DMF·4H2O}n (1) [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] has been synthesized solvothermally and structurally characterized by single-crystal X-ray diffraction. This compound shows significant selective CO2 uptake at low temperature. 1 exhibits antiferromagnetic properties below 17 K, confirmed by magnetic susceptibility measurements. Four new coordination polymers: {[Mn2(DBIBA)3]·ClO4·3DMF·3H2O}n (2), {[Mn2(DBIBA)3]×Cl×DMF×H2O}n (3), {[Mn2(DBIBA)3]×NO3×CH3OH×7H2O}n (4) and {[Mn2(DBIBA)3]×NO3×2CH3COCH3×H2O}n (5), have been synthesized from 1 via anion/solvent exchange protocols at room temperature.
dc.format.extent8 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec655077
dc.identifier.issn1528-7483
dc.identifier.urihttps://hdl.handle.net/2445/154179
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/cg500833s
dc.relation.ispartofCrystal Growth & Design, 2014, vol. 14, num. 11, p. 5585-5592
dc.relation.urihttps://doi.org/10.1021/cg500833s
dc.rights(c) American Chemical Society , 2014
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Química Inorgànica i Orgànica)
dc.subject.classificationLligands
dc.subject.classificationQuímica organometàl·lica
dc.subject.otherLigands
dc.subject.otherOrganometallic chemistry
dc.titleGas adsorption, magnetism, and single-crystal to single-crystal transformation studies of a three-dimensional Mn(II) porous coordination polymer
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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