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Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications

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dc.contributor.authorSalgado Pizarro, Rebeca
dc.contributor.authorNavarro-Rivero, M. E.
dc.contributor.authorDing, Y.
dc.contributor.authorBarreneche, Camila
dc.contributor.authorFernández Renna, Ana Inés
dc.date.accessioned2025-12-19T17:05:44Z
dc.date.available2025-12-19T17:05:44Z
dc.date.issued2024-10-15
dc.date.updated2025-12-19T17:05:44Z
dc.description.abstractLayered hybrid organic-inorganic perovskites (LHOIPs) have gained specific attention in applications such as optoelectronics. However, from the thermal perspective, these materials present a high potential for thermal energy storage applications in solid-state due to their heat storage capacity during their phase transitions. Here, we evaluate the first-order transition of these materials from the molecular point of view and make a relation with organic size, which is responsible for the ordering-disordering transition. Six LHOIPs have been synthesised, (C12H25N)2CuCl4, (C14H29N)2CuCl4, (C16H33N)2CuCl4, (C12H24N)2MnCl4, (C14H29N)2MnCl4 and (C16H33N)2MnCl4, where the crystal transformation has been evaluated under X-ray diffraction and Raman, and thermal conductivity as well as the thermal expansion have been studied. This work provides a comprehensive evaluation of the disordering phenomenon that is produced during phase transitions
dc.format.extent8 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec750546
dc.identifier.issn2352-152X
dc.identifier.urihttps://hdl.handle.net/2445/225073
dc.language.isoeng
dc.publisherElsevier
dc.relation.isformatofReproducció del document publicat a: https://doi.org/10.1016/j.est.2024.113483
dc.relation.ispartofJournal Of Energy Storage, 2024, vol. 100
dc.relation.urihttps://doi.org/10.1016/j.est.2024.113483
dc.rightscc-by-nc-nd (c) Salgado Pizarro, Rebeca, et al., 2024
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.classificationEspectroscòpia Raman
dc.subject.classificationCiència dels materials
dc.subject.classificationEmmagatzematge d'energia
dc.subject.otherRaman spectroscopy
dc.subject.otherMaterials science
dc.subject.otherStorage of energy
dc.titleThermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion

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