Iron hydride radical reductive alkylation of unactivated alkenes
| dc.contributor.author | Saladrigas, Mar | |
| dc.contributor.author | Bonjoch i Sesé, Josep | |
| dc.contributor.author | Bradshaw, Ben | |
| dc.date.accessioned | 2020-05-12T16:03:41Z | |
| dc.date.available | 2020-12-30T06:10:20Z | |
| dc.date.issued | 2019-12-30 | |
| dc.date.updated | 2020-05-12T16:03:41Z | |
| dc.description.abstract | Iron-catalyzed hydrogen atom transfer-mediated intermolecular C−C coupling reactions between alkenes and tosylhydrazones, followed by in situ cleavage of the tosylhydrazine intermediates using Et3N, are described. The process involves a new strategic bond disconnection resulting in the reductive alkylation of nonactivated alkenes. The reaction is operationally simple, proceeds under mild conditions, and has a wide substrate scope. | |
| dc.format.extent | 5 p. | |
| dc.format.mimetype | application/pdf | |
| dc.identifier.idgrec | 698797 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.pmid | 31887044 | |
| dc.identifier.uri | https://hdl.handle.net/2445/159735 | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.isformatof | Versió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.9b04459 | |
| dc.relation.ispartof | Organic Letters, 2019, vol. 22, num. 2, p. 684-688 | |
| dc.relation.uri | https://doi.org/10.1021/acs.orglett.9b04459 | |
| dc.rights | (c) American Chemical Society , 2019 | |
| dc.rights.accessRights | info:eu-repo/semantics/openAccess | |
| dc.source | Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica) | |
| dc.subject.classification | Alquens | |
| dc.subject.classification | Hidrogen | |
| dc.subject.other | Alkenes | |
| dc.subject.other | Hydrogen | |
| dc.title | Iron hydride radical reductive alkylation of unactivated alkenes | |
| dc.type | info:eu-repo/semantics/article | |
| dc.type | info:eu-repo/semantics/acceptedVersion |
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