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Iron hydride radical reductive alkylation of unactivated alkenes

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dc.contributor.authorSaladrigas, Mar
dc.contributor.authorBonjoch i Sesé, Josep
dc.contributor.authorBradshaw, Ben
dc.date.accessioned2020-05-12T16:03:41Z
dc.date.available2020-12-30T06:10:20Z
dc.date.issued2019-12-30
dc.date.updated2020-05-12T16:03:41Z
dc.description.abstractIron-catalyzed hydrogen atom transfer-mediated intermolecular C−C coupling reactions between alkenes and tosylhydrazones, followed by in situ cleavage of the tosylhydrazine intermediates using Et3N, are described. The process involves a new strategic bond disconnection resulting in the reductive alkylation of nonactivated alkenes. The reaction is operationally simple, proceeds under mild conditions, and has a wide substrate scope.
dc.format.extent5 p.
dc.format.mimetypeapplication/pdf
dc.identifier.idgrec698797
dc.identifier.issn1523-7060
dc.identifier.pmid31887044
dc.identifier.urihttps://hdl.handle.net/2445/159735
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.isformatofVersió postprint del document publicat a: https://doi.org/10.1021/acs.orglett.9b04459
dc.relation.ispartofOrganic Letters, 2019, vol. 22, num. 2, p. 684-688
dc.relation.urihttps://doi.org/10.1021/acs.orglett.9b04459
dc.rights(c) American Chemical Society , 2019
dc.rights.accessRightsinfo:eu-repo/semantics/openAccess
dc.sourceArticles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
dc.subject.classificationAlquens
dc.subject.classificationHidrogen
dc.subject.otherAlkenes
dc.subject.otherHydrogen
dc.titleIron hydride radical reductive alkylation of unactivated alkenes
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/acceptedVersion

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