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2009-05-01

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cc-by-nc (c) Pla Queral, Daniel et al., 2009
Please use this identifier to cite or link to this item: https://hdl.handle.net/2445/62365

The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H-pyrrolo[1,2-c]imidazolo[5,4-b]indole

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Abstract

N-3-(1-Methylindol-3-yl)propan-N-(2,2,2-trichloroethoxysulfonyl)guanidine was synthesized from 3-formyl-1-methylindole in six steps and subjected to conditions intended to convert the side-chain into a 2-iminotetrahydropyrimidine- containing product, of relevance to a possible synthesis of the aplicyanins. An alternative reaction course was observed, resulting in the formation of a new tetracyclic system.

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Síntesi orgànica, Medicaments antineoplàstics, Compostos de nitrogen, Aziridines, Àcids nucleics

Subject (English)

Organic synthesis, Antineoplastic agents, Nitrogen compounds, Aziridines, Nucleic acids

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Articles publicats en revistes (Farmacologia, Toxicologia i Química Terapèutica)
Articles publicats en revistes (Química Inorgànica i Orgànica)

Citation

PLA QUERAL, Daniel, et al. The synthesis of 1,2,3,6,6a,7-hexahydro-7-methyl-5-imino-1H-pyrrolo[1,2-c]imidazolo[5,4-b]indole. Arkivoc. 2009. Vol. 2009, num. 6, pags. 260-269. ISSN 1551-7012. [consulted: 10 of August of 2026]. Available at: https://hdl.handle.net/2445/62365

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